Let me spice this one a little - even when risking to add some confusion.

PK constraints do not require a unique index, you can create a PK on a non-unique index. Moreover, in some cases it is mandatory to do so - like when you are asking Oracle to defer contraints checking until the end of the transaction.

After you digest this one start thinking about the crazy (and useful) things you can do manipulating VALIDATE/NOVALIDATE and ENABLE/DISABLE option.

So, does in general a PK comes alongside a unique index? Yes... but that does not means it has to be unique.